Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries

Cyrus Koroni; Kiev Dixon; Pete Barnes; Dewen Hou; Luke Landsberg; Zihongbo Wang; Galib Grbic; Sarah Pooley; Sam Frisone; Tristan Olsen; Allison Muenzer; Dustin Nguyen; Blayze Bernal; Hui Xiong

doi:10.1021/acsnanoscienceau.3c00031

Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries

Cyrus Koroni, Kiev Dixon, Pete Barnes, Dewen Hou, Luke Landsberg, Zihongbo Wang, Galib Grbic, Sarah Pooley, Sam Frisone, Tristan Olsen, Allison Muenzer, Dustin Nguyen, Blayze Bernal, Hui Xiong

Integrated Energy & Storage Systems

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Niobium pentoxide (Nb₂O₅) is a promising negative electrode for sodium ion batteries (SIBs). By engineering the morphology and crystallinity of nanochanneled niobium oxides (NCNOs), the kinetic behavior and charge storage mechanism of Nb₂O₅ electrodes were investigated. Amorphous and crystalline NCNO samples were made by modulating anodization conditions (20−40 V and 140−180 °C) to synthesize nanostructures of varying pore sizes and wall thicknesses with identical chemical composition. The electrochemical energy storage properties of the NCNOs were studied, with the amorphous samples showing better overall rate performance than the crystalline samples. The enhanced rate performance of the amorphous samples is attributed to the higher capacitive contributions and Na-ion diffusivity analyzed from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT). It was found that the amorphous samples with smaller wall thicknesses facilitated improved kinetics. Among samples with similar pore size and wall thickness, the difference in their power performance stems from the crystallinity effect, which plays a more significant role in the resulting kinetics of the materials for Na-ion batteries.

Original language	English
Pages (from-to)	76-84
Number of pages	9
Journal	ACS Nanoscience Au
Volume	4
Issue number	1
Early online date	Nov 22 2023
DOIs	https://doi.org/10.1021/acsnanoscienceau.3c00031
State	E-pub ahead of print - Nov 22 2023

Keywords

charge storage and transport
crystallinity effect
morphology effect
nanochanneled niobium oxides
negative electrode materials
sodium ion batteries

INL Publication Number

INL/JOU-23-74873
163040

Access to Document

10.1021/acsnanoscienceau.3c00031

Cite this

Koroni, C., Dixon, K., Barnes, P., Hou, D., Landsberg, L., Wang, Z., Grbic, G., Pooley, S., Frisone, S., Olsen, T., Muenzer, A., Nguyen, D., Bernal, B., & Xiong, H. (2023). Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries. ACS Nanoscience Au, 4(1), 76-84. Advance online publication. https://doi.org/10.1021/acsnanoscienceau.3c00031

@article{950d608827784e6bbb969380514a1436,

title = "Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries",

abstract = "Niobium pentoxide (Nb2O5) is a promising negative electrode for sodium ion batteries (SIBs). By engineering the morphology and crystallinity of nanochanneled niobium oxides (NCNOs), the kinetic behavior and charge storage mechanism of Nb2O5 electrodes were investigated. Amorphous and crystalline NCNO samples were made by modulating anodization conditions (20−40 V and 140−180 °C) to synthesize nanostructures of varying pore sizes and wall thicknesses with identical chemical composition. The electrochemical energy storage properties of the NCNOs were studied, with the amorphous samples showing better overall rate performance than the crystalline samples. The enhanced rate performance of the amorphous samples is attributed to the higher capacitive contributions and Na-ion diffusivity analyzed from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT). It was found that the amorphous samples with smaller wall thicknesses facilitated improved kinetics. Among samples with similar pore size and wall thickness, the difference in their power performance stems from the crystallinity effect, which plays a more significant role in the resulting kinetics of the materials for Na-ion batteries.",

keywords = "charge storage and transport, crystallinity effect, morphology effect, nanochanneled niobium oxides, negative electrode materials, sodium ion batteries",

author = "Cyrus Koroni and Kiev Dixon and Pete Barnes and Dewen Hou and Luke Landsberg and Zihongbo Wang and Galib Grbic and Sarah Pooley and Sam Frisone and Tristan Olsen and Allison Muenzer and Dustin Nguyen and Blayze Bernal and Hui Xiong",

note = "Funding Information: This work was supported by the U.S. National Science Foundation (NSF) grant numbers DMR-1454984 and DMR-1838604. C.K. acknowledges the support of the NASA Idaho Space Grant Consortium (ISGC) fellowship. Works by G. Grbic{\textquoteright} and B. Bernal were supported by ACS and the Project SEED endowment. Work by S.F. was supported by NSF Undergraduate Research Experience (REU) program (DMR- 1950305). Work by S.P. was supported by NSF Louis Stokes Alliance for Minority Participation (LSAMP) REU program. Work by A.M. was supported by the Higher Education Research Council (HERC) Fellowship. Work performed at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility, was supported by the U.S. DOE, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. P.B. thanks E. Dufek from Idaho National Laboratory for helpful discussions throughout the project. Publisher Copyright: {\textcopyright} 2023 The Authors. Published by American Chemical Society.",

year = "2023",

month = nov,

day = "22",

doi = "10.1021/acsnanoscienceau.3c00031",

language = "English",

volume = "4",

pages = "76--84",

journal = "ACS Nanoscience Au",

issn = "2694-2496",

publisher = "American Chemical Society",

number = "1",

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TY - JOUR

T1 - Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries

AU - Koroni, Cyrus

AU - Dixon, Kiev

AU - Barnes, Pete

AU - Hou, Dewen

AU - Landsberg, Luke

AU - Wang, Zihongbo

AU - Grbic, Galib

AU - Pooley, Sarah

AU - Frisone, Sam

AU - Olsen, Tristan

AU - Muenzer, Allison

AU - Nguyen, Dustin

AU - Bernal, Blayze

AU - Xiong, Hui

N1 - Funding Information: This work was supported by the U.S. National Science Foundation (NSF) grant numbers DMR-1454984 and DMR-1838604. C.K. acknowledges the support of the NASA Idaho Space Grant Consortium (ISGC) fellowship. Works by G. Grbic’ and B. Bernal were supported by ACS and the Project SEED endowment. Work by S.F. was supported by NSF Undergraduate Research Experience (REU) program (DMR- 1950305). Work by S.P. was supported by NSF Louis Stokes Alliance for Minority Participation (LSAMP) REU program. Work by A.M. was supported by the Higher Education Research Council (HERC) Fellowship. Work performed at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility, was supported by the U.S. DOE, Office of Basic Energy Sciences, under Contract No. DE-AC02-06CH11357. P.B. thanks E. Dufek from Idaho National Laboratory for helpful discussions throughout the project. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society.

PY - 2023/11/22

Y1 - 2023/11/22

N2 - Niobium pentoxide (Nb2O5) is a promising negative electrode for sodium ion batteries (SIBs). By engineering the morphology and crystallinity of nanochanneled niobium oxides (NCNOs), the kinetic behavior and charge storage mechanism of Nb2O5 electrodes were investigated. Amorphous and crystalline NCNO samples were made by modulating anodization conditions (20−40 V and 140−180 °C) to synthesize nanostructures of varying pore sizes and wall thicknesses with identical chemical composition. The electrochemical energy storage properties of the NCNOs were studied, with the amorphous samples showing better overall rate performance than the crystalline samples. The enhanced rate performance of the amorphous samples is attributed to the higher capacitive contributions and Na-ion diffusivity analyzed from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT). It was found that the amorphous samples with smaller wall thicknesses facilitated improved kinetics. Among samples with similar pore size and wall thickness, the difference in their power performance stems from the crystallinity effect, which plays a more significant role in the resulting kinetics of the materials for Na-ion batteries.

AB - Niobium pentoxide (Nb2O5) is a promising negative electrode for sodium ion batteries (SIBs). By engineering the morphology and crystallinity of nanochanneled niobium oxides (NCNOs), the kinetic behavior and charge storage mechanism of Nb2O5 electrodes were investigated. Amorphous and crystalline NCNO samples were made by modulating anodization conditions (20−40 V and 140−180 °C) to synthesize nanostructures of varying pore sizes and wall thicknesses with identical chemical composition. The electrochemical energy storage properties of the NCNOs were studied, with the amorphous samples showing better overall rate performance than the crystalline samples. The enhanced rate performance of the amorphous samples is attributed to the higher capacitive contributions and Na-ion diffusivity analyzed from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT). It was found that the amorphous samples with smaller wall thicknesses facilitated improved kinetics. Among samples with similar pore size and wall thickness, the difference in their power performance stems from the crystallinity effect, which plays a more significant role in the resulting kinetics of the materials for Na-ion batteries.

KW - charge storage and transport

KW - crystallinity effect

KW - morphology effect

KW - nanochanneled niobium oxides

KW - negative electrode materials

KW - sodium ion batteries

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U2 - 10.1021/acsnanoscienceau.3c00031

DO - 10.1021/acsnanoscienceau.3c00031

M3 - Article

AN - SCOPUS:85179779354

SN - 2694-2496

VL - 4

SP - 76

EP - 84

JO - ACS Nanoscience Au

JF - ACS Nanoscience Au

IS - 1

ER -

Morphology and Crystallinity Effects of Nanochanneled Niobium Oxide Electrodes for Na-Ion Batteries

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