Abstract
The electrical characteristics of positive temperature coefficient resistance (PTCR effects) mainly come from the grain boundary. The useful way to enhance electrical characteristics of PTC ceramics is to decrease the grain size and add the number of grain boundary. In the paper, the grain size and PTCR effects of ceramics were investigated on the effects of the molar ratio of donor and acceptor, the sintering process and high-energy ball milling. The formulation of prepared ceramics were Ba0.8Sr0.2Ti1.01-O3 + 0.03 mol% Mn(NO3)2 + x mol Y2O3 + 2 wt% SiO2. The grain size of these PTC ceramics was decreased to only 1-2 μm by adding Sr2+ and Y3+ to substitute the A-site barium ions, which were calcined at 1220 °C and sintered at 1300 °C after high-energy ball milling for powders. The prepared ceramics exhibited room temperature resistivity of 100 Ω cm, resistance rising rate more than 104 unit through the Curie temperature, and relative density between 75% and 90%.
| Original language | English |
|---|---|
| Pages (from-to) | 106-110 |
| Number of pages | 5 |
| Journal | Microelectronic Engineering |
| Volume | 103 |
| DOIs | |
| State | Published - Mar 2013 |
| Externally published | Yes |
Keywords
- BaTiO
- Donor and acceptor
- Fine-grained
- PTC
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