Selectivity for water isotopologues within metal organic nanotubes

Maurice K. Payne; Lindsey C. Applegate; Priyanka Singh; Ashini S. Jayasinghe; George B. Crull; Andrea B. Grafton; Christopher M. Cheatum; Tori Z. Forbes

doi:10.1039/d1ra00602a

Selectivity for water isotopologues within metal organic nanotubes

Maurice K. Payne
, Lindsey C. Applegate
, Priyanka Singh
, Ashini S. Jayasinghe
, George B. Crull
, Andrea B. Grafton
, Christopher M. Cheatum
, Tori Z. Forbes

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H2O over all types of heavy water (D2O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.

Original language	English
Pages (from-to)	16706-16710
Number of pages	5
Journal	RSC Advances
Volume	11
Issue number	27
DOIs	https://doi.org/10.1039/d1ra00602a
State	Published - Apr 23 2021
Externally published	Yes

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10.1039/d1ra00602a

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title = "Selectivity for water isotopologues within metal organic nanotubes",

abstract = "Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H2O over all types of heavy water (D2O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.",

author = "Payne, \{Maurice K.\} and Applegate, \{Lindsey C.\} and Priyanka Singh and Jayasinghe, \{Ashini S.\} and Crull, \{George B.\} and Grafton, \{Andrea B.\} and Cheatum, \{Christopher M.\} and Forbes, \{Tori Z.\}",

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T1 - Selectivity for water isotopologues within metal organic nanotubes

AU - Payne, Maurice K.

AU - Applegate, Lindsey C.

AU - Singh, Priyanka

AU - Jayasinghe, Ashini S.

AU - Crull, George B.

AU - Grafton, Andrea B.

AU - Cheatum, Christopher M.

AU - Forbes, Tori Z.

PY - 2021/4/23

Y1 - 2021/4/23

N2 - Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H2O over all types of heavy water (D2O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.

AB - Through a combination of many analytical approaches, we show that a metal organic nanotube (UMON) displays selectivity for H2O over all types of heavy water (D2O, HDO, HTO). Water adsorption experiments combined with vibrational and radiochemical analyses reveal significant differences in uptake and suggest that surface adsorption processes may be a key driver in water uptake for this material.

UR - https://www.scopus.com/pages/publications/85105792852

U2 - 10.1039/d1ra00602a

DO - 10.1039/d1ra00602a

M3 - Article

AN - SCOPUS:85105792852

SN - 2046-2069

VL - 11

SP - 16706

EP - 16710

JO - RSC Advances

JF - RSC Advances

IS - 27

ER -

Selectivity for water isotopologues within metal organic nanotubes

Abstract

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