TY - GEN
T1 - Progressing zirconium-alloy corrosion models using synchrotron xanes
AU - Moorehead, Michael
AU - Couet, Adrien
AU - Hu, Jing
AU - Cai, Zhonghou
N1 - Funding Information:
The authors would like to thank those at Westinghouse for providing the samples used in this experiment as well as those at Oxford University and in the MUZIC community. This research used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under Contract No. DE-AC02-06CH11357.
Publisher Copyright:
© 2019, The Minerals, Metals & Materials Society.
PY - 2019
Y1 - 2019
N2 - The corrosion and hydrogen pickup of in-reactor zirconium-based cladding is currently limiting the maximum fuel burnup in light-water reactors. Since the oxidation rate and hydrogen pickup fraction of zirconium alloys vary significantly as a function of exposure time, burnup, and alloy composition, it is critical to better understand the underlying mechanisms to model and predict corrosion behavior. Following the analysis of ~500 autoclave coupons, a physically based zirconium-alloy corrosion model founded on first principles, named “Coupled Current Charge Compensation (C4)”, has been developed. The model reproduces the differences in oxidation kinetics and hydrogen pickup between different zirconium alloys, such as Zr-Nb and Zircaloy-4. Since oxidized solute elements affect the corrosion process through a space-charge compensation mechanism, synchrotron nano-beam X-ray Absorption Near-Edge Spectroscopy has been performed on multiple oxidized Zr-Nb alloys to determine the oxidation-state profile of niobium in the oxide layer. The results inform the C4 model and the associated hydrogen pickup fraction.
AB - The corrosion and hydrogen pickup of in-reactor zirconium-based cladding is currently limiting the maximum fuel burnup in light-water reactors. Since the oxidation rate and hydrogen pickup fraction of zirconium alloys vary significantly as a function of exposure time, burnup, and alloy composition, it is critical to better understand the underlying mechanisms to model and predict corrosion behavior. Following the analysis of ~500 autoclave coupons, a physically based zirconium-alloy corrosion model founded on first principles, named “Coupled Current Charge Compensation (C4)”, has been developed. The model reproduces the differences in oxidation kinetics and hydrogen pickup between different zirconium alloys, such as Zr-Nb and Zircaloy-4. Since oxidized solute elements affect the corrosion process through a space-charge compensation mechanism, synchrotron nano-beam X-ray Absorption Near-Edge Spectroscopy has been performed on multiple oxidized Zr-Nb alloys to determine the oxidation-state profile of niobium in the oxide layer. The results inform the C4 model and the associated hydrogen pickup fraction.
KW - C4 Model
KW - XANES
KW - Zirconium corrosion
UR - https://www.scopus.com/pages/publications/85064066242
U2 - 10.1007/978-3-030-04639-2_120
DO - 10.1007/978-3-030-04639-2_120
M3 - Conference contribution
AN - SCOPUS:85064066242
SN - 9783030046385
SN - 9783030046392
SN - 9783319515403
SN - 9783319651354
SN - 9783319728520
SN - 9783319950211
T3 - Minerals, Metals and Materials Series
SP - 1781
EP - 1792
BT - Minerals, Metals and Materials Series
PB - Springer International Publishing
T2 - 18th International Conference on Environmental Degradation of Materials in Nuclear Power Systems – Water Reactors 2019
Y2 - 18 August 2019 through 22 August 2019
ER -