Preperation of Br-Doped Li4Ti5O12 Anode and Its Electrochemical Performance in Li-Ion Battery

In this work, we studied about Br-doped Li4Ti5O12-xBrx (“x”= 0, 0.1, 0.3, 0.5 and 0.7) anode materials, which were synthesized by a conventional solid-state reaction using precursors of Li2CO3, TiO2 and LiBr, and we found that their electrochemical properties were related to the doping behavior Most of the Br ions are situated on the surfaces/interfaces of agglomerated particles rather than in the bulk lattice after quantitative instrumental analysis. This lead to the formation of Narrow conduction paths of electron and Li-ion on their surfaces/interfaces. The presence of these narrow surface electrical conduits increased the rate-capability of the LTOBr samples during charging/discharging process. Highly Br-doped sample (LTOBr0.7) showed a slight reduction in capacity. The LTOBr0.5 sample, by the mean time, showed the highest capacity of 125 mAh/g at 1C compared to 115 mAh/g for pure LTO. This was explained with the formation of fine precipitations (Br-containing second phase) on the surfaces of the LTO particles due to high Br addition. The formation of fine precipitations (Br-containing second phase) on the surfaces of the LTO particles due to high Br addition could be the explanation of this.