Porous ion emitters-A new type of thermal ion emitter

M. G. Watrous, James E. Delmore, Mark L. Stone

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

A new type of porous refractory material has been developed as a thermal ionization emitter that is an improvement over both direct filament and resin bead loading. The porous ion emitter is sintered onto the center of a conventional thermal ionization filament and an aqueous solution containing the sample wicked into this emitter. Application of the porous ion emitter to uranium is demonstrated to provide a utilization efficiency ranging between 1% and 2% across a sample size range of 0.2-10. pg, better than that achieved from resin beads and much better than that achieved with direct loading onto a filament. The technique improves sensitivity and reduces the chance of losing a high value sample when manipulating a single resin bead containing an entire sample.

Original languageEnglish
Pages (from-to)21-24
Number of pages4
JournalInternational Journal of Mass Spectrometry
Volume296
Issue number1-3
DOIs
StatePublished - Sep 2010

Keywords

  • Porous ion emitter
  • TIMS
  • Uranium

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