Nature of hydrogen interactions with Ni(II) complexes containing cyclic phosphine ligands with pendant nitrogen bases

Keyphrases

• Proton 100%
• Nitrogenous Bases 100%
• Ni(II) Complex 100%
• Phosphine Ligands 100%
• Cyclic Aminomethylphosphines 100%
• Hydrogen Interaction 100%
• Two Dimensional 50%
• Electrochemical Oxidation 50%
• Acetonitrile 50%
• Hydrogen Production 50%
• Electrochemical Production 50%
• Hydride Complexes 50%
• Hydrogen Oxidation 50%
• H2 Production 50%
• Amines 50%
• Nickel Catalyst 50%
• Turnover Frequency 50%
• Molecular Catalyst 50%
• Diphosphine Ligand 50%
• Proton Relay 50%
• High Catalytic Activity 50%
• Cyclohexyl 50%
• Benzyl 50%
• Diazabicyclooctane 50%
• Deprotonation 50%
• Hydrogen Addition 50%
• Hydrogenase 50%
• Cyclic Ligand 50%
• Hydrogen Activation 50%
• Energy Difference 50%
• 1H{31P} 50%
• 31P NMR Spectroscopy 50%
• Protonated Amine 50%
• 1H NMR Spectroscopy 50%
• Nickel Hydride 50%
• Electron Density 50%
• Fe-hydrogenase 50%
• Dihydrogen 50%
• Electrocatalytic 50%
• Small Energy 50%
• H2 Production Rate 50%
• NiFe 50%
• 15N NMR Spectroscopy 50%

Chemistry

• Electrochemical Oxidation 100%
• Catalyst Activity 100%
• BF 4 100%
• Base 100%
• Turnover Frequency 100%
• Electron Density 100%
• Phosphorus-31 Magnetic Resonance Spectroscopy 100%
• Dihydrogen 100%
• 1H NMR Spectroscopy 100%
• Deprotonation 100%
• Hydrogenase 100%
• 15N NMR Spectroscopy 100%

Material Science

• Hydride 100%
• Catalyst Activity 100%
• Hydrogenase 100%
• Nuclear Magnetic Resonance Spectroscopy 100%
• Carrier Concentration 100%