Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface

Daniel J. Murray; Dustin D. Patterson; Payam Payamyar; Radha Bhola; Wentao Song; Markus Lackinger; A. Dieter Schlüter; Benjamin T. King

doi:10.1021/ja512018j

Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface

Daniel J. Murray
, Dustin D. Patterson
, Payam Payamyar
, Radha Bhola
, Wentao Song
, Markus Lackinger
, A. Dieter Schlüter
, Benjamin T. King

Materials and Fuels Complex

Research output: Contribution to journal › Article › peer-review

215 Scopus citations

Abstract

We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.

Original language	English
Pages (from-to)	3450-3453
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	10
DOIs	https://doi.org/10.1021/ja512018j
State	Published - Mar 18 2015

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10.1021/ja512018j

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abstract = "We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.",

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AU - Murray, Daniel J.

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AU - Payamyar, Payam

AU - Bhola, Radha

AU - Song, Wentao

AU - Lackinger, Markus

AU - Schlüter, A. Dieter

AU - King, Benjamin T.

PY - 2015/3/18

Y1 - 2015/3/18

N2 - We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.

AB - We present the synthesis of a two-dimensional polymer at the air/water interface and its nm-resolution imaging. Trigonal star, amphiphilic monomers bearing three anthraceno groups on a central triptycene core are confined at the air/water interface. Compression followed by photopolymerization on the interface provides the two-dimensional polymer. Analysis by scanning tunneling microscopy suggests that the polymer is periodic with ultrahigh pore density.

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M3 - Article

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Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface

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