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High pressure synthesis and magnetic properties of cubic B20 MnGe and CoGe

  • A. V. Tsvyashchenko
  • , V. A. Sidorov
  • , L. N. Fomicheva
  • , V. N. Krasnorussky
  • , R. A. Sadykov
  • , J. D. Thompson
  • , K. Gofryk
  • , F. Ronning
  • , V. Yu Ivanov

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

21 Scopus citations

Abstract

Samples of MnGe and CoGe having cubic B20 structure were prepared at high pressure. Magnetic measurements showed that CoGe is a Pauli paramagnet, but MnGe exhibits antiferromagnetic-type ordering below TN = 175 K. The magnetic susceptibility of MnGe follows a Curie-Weiss law above 300 K with an effective magnetic moment μeff = 3.68 μB/f.u. and θp = + 231 K. The large positive value of θp indicates a strong ferromagnetic exchange. The value of the effective moment is close to the free Mn4+ ion (4F3/2) value 3.87 μB/f.u. From measurements of the magnetization of MnGe in fields up to 60 kOe and in the temperature range 2-350 K, we constructed its T-H magnetic phase diagram which is similar to that proposed for MnSi-type compounds with helical magnetic order. Specific heat measurements reveal that the total magnetic entropy of MnGe relative to nonmagnetic CoGe is equal to 3.55 J/mole-K (0.62Rln2).

Original languageEnglish
Title of host publicationMagnetism and Magnetic Materials V
PublisherTrans Tech Publications Ltd
Pages225-228
Number of pages4
ISBN (Print)9783037854365
DOIs
StatePublished - 2012
Event5th Moscow International Symposium on Magnetism, MISM 2011 - Moscow, Russian Federation
Duration: Aug 21 2011Aug 25 2011

Publication series

NameSolid State Phenomena
Volume190
ISSN (Print)1012-0394

Conference

Conference5th Moscow International Symposium on Magnetism, MISM 2011
Country/TerritoryRussian Federation
CityMoscow
Period08/21/1108/25/11

Keywords

  • B20 structure
  • CoGe
  • Helimagnet
  • High pressure synthesis
  • Magnetization
  • MnGe
  • Specific heat

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