TY - JOUR
T1 - Green biomass processing to lower slurry viscosity and reduce biofuel cost
AU - Williams, C. Luke
AU - Karlsson, Mikael C.F.
AU - Emerson, Rachel M.
AU - Smith, William A.
AU - Bhattacharjee, Tiasha
N1 - Funding Information:
Work supported through the INL Laboratory Directed Research& Development (LDRD) Program under DOE Idaho Operations Office Contract DE-AC07-05ID14517 . The views expressed in the article do not necessarily represent the views of the United States Department of Energy or the United States Government.
Publisher Copyright:
© 2022 Elsevier Ltd
PY - 2022/10
Y1 - 2022/10
N2 - Sustainable fuels for industries that cannot be easily electrified, like aviation and marine, will be crucial to achieving a carbon neutral economy. Processing wet solids through a process like hydrothermal liquifaction to produce upgradeable bio-oil is one pathway that could transform high moisture waste into a fuel. This work pioneers two green processing pathways to produce a biomass feedstock for liquefaction that is far less viscous at higher solids loadings than traditional slurries. This decrease in viscosity could significantly improve the profitability of producing fuels through slurry-based conversion processes. Natural biological degradation of corn stover before grinding has been shown to lower slurry viscosity by a factor of three and torrefaction has been shown to produce slurries that are 150x less viscous than the original material. Additionally, new insight has been gained into the critical physical and chemical parameters that impact slurry viscosity. Common parameters in slurry processing, like the average particle size, shear rate, and solids loadings clearly control viscosity, and these results are confirmed for biomass. Additionally, new physical parameters like aspect ratio and sphericity, as well as chemical parameters like extractives content, non-structural sugars, and zeta potential have been shown to impact and be good predictors of slurry viscosity and processability.
AB - Sustainable fuels for industries that cannot be easily electrified, like aviation and marine, will be crucial to achieving a carbon neutral economy. Processing wet solids through a process like hydrothermal liquifaction to produce upgradeable bio-oil is one pathway that could transform high moisture waste into a fuel. This work pioneers two green processing pathways to produce a biomass feedstock for liquefaction that is far less viscous at higher solids loadings than traditional slurries. This decrease in viscosity could significantly improve the profitability of producing fuels through slurry-based conversion processes. Natural biological degradation of corn stover before grinding has been shown to lower slurry viscosity by a factor of three and torrefaction has been shown to produce slurries that are 150x less viscous than the original material. Additionally, new insight has been gained into the critical physical and chemical parameters that impact slurry viscosity. Common parameters in slurry processing, like the average particle size, shear rate, and solids loadings clearly control viscosity, and these results are confirmed for biomass. Additionally, new physical parameters like aspect ratio and sphericity, as well as chemical parameters like extractives content, non-structural sugars, and zeta potential have been shown to impact and be good predictors of slurry viscosity and processability.
UR - https://www.scopus.com/pages/publications/85136595124
UR - https://www.mendeley.com/catalogue/cfacbf23-5c6a-3cf1-b8c2-12de52bc52cb/
U2 - 10.1016/j.biombioe.2022.106566
DO - 10.1016/j.biombioe.2022.106566
M3 - Article
AN - SCOPUS:85136595124
SN - 0961-9534
VL - 165
JO - Biomass and Bioenergy
JF - Biomass and Bioenergy
M1 - 106566
ER -