Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

Amy E. Kynman; Travis S. Grimes; Stephen P. Mezyk; Bobby Layne; Andrew R. Cook; Brian M. Rotermund; Gregory P. Horne

doi:10.1039/d4dt00991f

Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

Amy E. Kynman, Travis S. Grimes, Stephen P. Mezyk, Bobby Layne, Andrew R. Cook, Brian M. Rotermund, Gregory P. Horne

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4 Scopus citations

Abstract

First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(iv) in concentrated (6.0 M) HNO₃, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO₃˙ and Am(iii).

Original language	English
Pages (from-to)	9262-9266
Number of pages	5
Journal	Dalton Transactions
Volume	53
Issue number	22
Early online date	May 22 2024
DOIs	https://doi.org/10.1039/d4dt00991f
State	E-pub ahead of print - May 22 2024

INL Publication Number

INL/CON-24-79909
182758

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10.1039/d4dt00991f

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title = "Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis",

abstract = "First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(iv) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3˙ and Am(iii).",

author = "Kynman, {Amy E.} and Grimes, {Travis S.} and Mezyk, {Stephen P.} and Bobby Layne and Cook, {Andrew R.} and Rotermund, {Brian M.} and Horne, {Gregory P.}",

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AU - Kynman, Amy E.

AU - Grimes, Travis S.

AU - Mezyk, Stephen P.

AU - Layne, Bobby

AU - Cook, Andrew R.

AU - Rotermund, Brian M.

AU - Horne, Gregory P.

PY - 2024/5/22

Y1 - 2024/5/22

N2 - First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(iv) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3˙ and Am(iii).

AB - First-of-a-kind temperature-controlled electron pulse radiolysis experiments facilitated the radiation-induced formation of Am(iv) in concentrated (6.0 M) HNO3, and enabled the derivation of Arrhenius and Eyring activation parameters for instigating the radical reaction between NO3˙ and Am(iii).

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M3 - Article

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 22

ER -

Generation and study of Am(iv) by temperature-controlled electron pulse radiolysis

Abstract

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