TY - GEN
T1 - Dopant Compensation Within the Intrinsic poly-Si Isolation Region in poly-Si/SiOx Passivated IBC Si Solar Cells
AU - Hartenstein, Matthew B.
AU - Stetson, Caleb
AU - Nemeth, William
AU - Harvey, Steve
AU - Agarwal, Sumit
AU - Stradins, Pauls
N1 - Funding Information:
This research was supported by US DOE EERE under the Photovoltaic Research and Development (PVRD) program of the Solar Energy Technology Office under Award Number DE-EE0007553 and NREL Core Si award DE-EE00034359. The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes.
Funding Information:
This research was supported by US DOE EERE under the Photovoltaic Research and Development (PVRD) program of the Solar Energy Technology Office under Award Number DE-EE0007553 and NREL Core Si award DEEE00034359. The views expressed in the article do not necessarily represent the views of the DOE or the U.S. Government. The U.S. Government retains and the publisher, by accepting the article for publication, acknowledges that the U.S. Government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for U.S. Government purposes.
Publisher Copyright:
© 2022 American Institute of Physics Inc.. All rights reserved.
PY - 2022/8/24
Y1 - 2022/8/24
N2 - We report on the effect of dopant compensation within intrinsic poly-Si regions between p- and n-type fingers of poly-Si/SiOx passivated interdigitated back contact (IBC) solar cells using intrinsic poly-Si as the isolation region between the doped poly-Si fingers. First, we show that dopants from the doped fingers contaminate the intrinsic gap, resulting in doping of the entire intrinsic gap and overlap of the dopant tails from each finger. Next, we show that despite this doping across the gap, shunting between the doped fingers does not occur. We show that this is a result of trap-assisted compensation creating a highly resistive intrinsic region, preventing shunt. We simulate shunt resistance across the gap based on local carrier concentration and deep trap density. We show that trap defects within the poly-Si enhance compensation between the dopant tails. We experimentally confirm these predictions by scanning spreading resistance microscopy of the gap showing ~20 µm domain with resistivity ~ 107 Ω cm. Additionally, Kelvin probe force microscopy are compared to finite element simulations which result in the same approximate shape for potential profile, indicating diode behavior across the isolation region. These results demonstrate the powerful effect that trap defects have within the poly-Si isolation region and suggest that precision patterning is not as essential as once thought.
AB - We report on the effect of dopant compensation within intrinsic poly-Si regions between p- and n-type fingers of poly-Si/SiOx passivated interdigitated back contact (IBC) solar cells using intrinsic poly-Si as the isolation region between the doped poly-Si fingers. First, we show that dopants from the doped fingers contaminate the intrinsic gap, resulting in doping of the entire intrinsic gap and overlap of the dopant tails from each finger. Next, we show that despite this doping across the gap, shunting between the doped fingers does not occur. We show that this is a result of trap-assisted compensation creating a highly resistive intrinsic region, preventing shunt. We simulate shunt resistance across the gap based on local carrier concentration and deep trap density. We show that trap defects within the poly-Si enhance compensation between the dopant tails. We experimentally confirm these predictions by scanning spreading resistance microscopy of the gap showing ~20 µm domain with resistivity ~ 107 Ω cm. Additionally, Kelvin probe force microscopy are compared to finite element simulations which result in the same approximate shape for potential profile, indicating diode behavior across the isolation region. These results demonstrate the powerful effect that trap defects have within the poly-Si isolation region and suggest that precision patterning is not as essential as once thought.
UR - http://www.scopus.com/inward/record.url?scp=85137510133&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/d5d15972-5c0c-3fe9-8247-206451bf8a17/
U2 - 10.1063/5.0090546
DO - 10.1063/5.0090546
M3 - Conference contribution
AN - SCOPUS:85137510133
T3 - AIP Conference Proceedings
BT - SiliconPV 2021 - 11th International Conference on Crystalline Silicon Photovoltaics
A2 - Brendel, Rolf
A2 - Ballif, Christophe
A2 - Dubois, Sebastien
A2 - Glunz, Stefan
A2 - Hahn, Giso
A2 - Poortmans, Jef
A2 - Verlinden, Pierre
A2 - Weeber, Arthur
PB - American Institute of Physics Inc.
T2 - 11th International Conference on Crystalline Silicon Photovoltaics, SiliconPV 2021
Y2 - 19 April 2021 through 23 April 2021
ER -