Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide

Ling Feng He; Paul Roman; Bin Leng; Kumar Sridharan; Mark Anderson; Todd R. Allen

doi:10.1016/j.corsci.2013.12.023

Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide

Ling Feng He
, Paul Roman
, Bin Leng
, Kumar Sridharan
, Mark Anderson
, Todd R. Allen

Materials and Fuels Complex

Research output: Contribution to journal › Article › peer-review

122 Scopus citations

Abstract

Microstructure characterization of corrosion behavior of an alumina forming austenitic (AFA) steel exposed to supercritical carbon dioxide was conducted at 450-650°C and 20MPa. At low temperature and short exposure times, the oxidation kinetics were parabolic and the oxide scales were mainly composed of protective and continuous Al₂O₃ and (Cr, Mn)-rich oxide layers. As the temperature and exposure time increased, the AFA steel gradually suffered breakaway oxidation and its oxide scales showed a multilayer structure mainly composed of Fe₃O₄, (Cr, Fe)₃O₄, NiFe/FeCr₂O₄/Cr₂O₃/Al₂O₃, FeCr₂O₄/Al₂O₃, and NiFe/Cr₂O₃/Al₂O₃, in sequence. The corrosion mechanism based on the microstructure evolution is discussed in detail.

Original language	English
Pages (from-to)	67-76
Number of pages	10
Journal	Corrosion Science
Volume	82
DOIs	https://doi.org/10.1016/j.corsci.2013.12.023
State	Published - May 2014

Keywords

A. Stainless steels
B. SEM
B. STEM
C. Carburization
C. High temperature corrosion
C. Oxidation

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10.1016/j.corsci.2013.12.023

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@article{a3d9e1c609ac41d29b7539c62158b10d,

title = "Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide",

abstract = "Microstructure characterization of corrosion behavior of an alumina forming austenitic (AFA) steel exposed to supercritical carbon dioxide was conducted at 450-650°C and 20MPa. At low temperature and short exposure times, the oxidation kinetics were parabolic and the oxide scales were mainly composed of protective and continuous Al2O3 and (Cr, Mn)-rich oxide layers. As the temperature and exposure time increased, the AFA steel gradually suffered breakaway oxidation and its oxide scales showed a multilayer structure mainly composed of Fe3O4, (Cr, Fe)3O4, NiFe/FeCr2O4/Cr2O3/Al2O3, FeCr2O4/Al2O3, and NiFe/Cr2O3/Al2O3, in sequence. The corrosion mechanism based on the microstructure evolution is discussed in detail.",

keywords = "A. Stainless steels, B. SEM, B. STEM, C. Carburization, C. High temperature corrosion, C. Oxidation",

author = "He, \{Ling Feng\} and Paul Roman and Bin Leng and Kumar Sridharan and Mark Anderson and Allen, \{Todd R.\}",

note = "Funding Information: The authors would like to thank Michael P. Brady, from the Materials Science and Technology Division at Oak Ridge National Laboratory, USA for providing the test AFA steels. This work has been supported by the U.S. Department of Energy through NEUP and by the National Renewable Energy Laboratory and completed in part using the NSF-supported shared facilities at the University of Wisconsin.",

year = "2014",

month = may,

doi = "10.1016/j.corsci.2013.12.023",

language = "English",

volume = "82",

pages = "67--76",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide

AU - He, Ling Feng

AU - Roman, Paul

AU - Leng, Bin

AU - Sridharan, Kumar

AU - Anderson, Mark

AU - Allen, Todd R.

N1 - Funding Information: The authors would like to thank Michael P. Brady, from the Materials Science and Technology Division at Oak Ridge National Laboratory, USA for providing the test AFA steels. This work has been supported by the U.S. Department of Energy through NEUP and by the National Renewable Energy Laboratory and completed in part using the NSF-supported shared facilities at the University of Wisconsin.

PY - 2014/5

Y1 - 2014/5

N2 - Microstructure characterization of corrosion behavior of an alumina forming austenitic (AFA) steel exposed to supercritical carbon dioxide was conducted at 450-650°C and 20MPa. At low temperature and short exposure times, the oxidation kinetics were parabolic and the oxide scales were mainly composed of protective and continuous Al2O3 and (Cr, Mn)-rich oxide layers. As the temperature and exposure time increased, the AFA steel gradually suffered breakaway oxidation and its oxide scales showed a multilayer structure mainly composed of Fe3O4, (Cr, Fe)3O4, NiFe/FeCr2O4/Cr2O3/Al2O3, FeCr2O4/Al2O3, and NiFe/Cr2O3/Al2O3, in sequence. The corrosion mechanism based on the microstructure evolution is discussed in detail.

AB - Microstructure characterization of corrosion behavior of an alumina forming austenitic (AFA) steel exposed to supercritical carbon dioxide was conducted at 450-650°C and 20MPa. At low temperature and short exposure times, the oxidation kinetics were parabolic and the oxide scales were mainly composed of protective and continuous Al2O3 and (Cr, Mn)-rich oxide layers. As the temperature and exposure time increased, the AFA steel gradually suffered breakaway oxidation and its oxide scales showed a multilayer structure mainly composed of Fe3O4, (Cr, Fe)3O4, NiFe/FeCr2O4/Cr2O3/Al2O3, FeCr2O4/Al2O3, and NiFe/Cr2O3/Al2O3, in sequence. The corrosion mechanism based on the microstructure evolution is discussed in detail.

KW - A. Stainless steels

KW - B. SEM

KW - B. STEM

KW - C. Carburization

KW - C. High temperature corrosion

KW - C. Oxidation

UR - https://www.scopus.com/pages/publications/84894736865

U2 - 10.1016/j.corsci.2013.12.023

DO - 10.1016/j.corsci.2013.12.023

M3 - Article

AN - SCOPUS:84894736865

SN - 0010-938X

VL - 82

SP - 67

EP - 76

JO - Corrosion Science

JF - Corrosion Science

ER -

Corrosion behavior of an alumina forming austenitic steel exposed to supercritical carbon dioxide

Abstract

Keywords

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