Copper β-diketonate molecular squares and their host-guest reactions

Chandi Pariya; Christopher R. Sparrow; Chang Keun Back; Giselle Sandí; Frank R. Fronczek; Andrew W. Maverick

doi:10.1002/anie.200701252

Copper β-diketonate molecular squares and their host-guest reactions

Chandi Pariya
, Christopher R. Sparrow
, Chang Keun Back
, Giselle Sandí
, Frank R. Fronczek
, Andrew W. Maverick

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

(Figure Presented) All square: Treatment of m-phenylene-bis(β- diketones) with [Cu(NH₃)₄]²⁺ yields molecular squares rather than the expected hexagons. The squares react readily with guests such as C₆₀ (see structure) and 4,4′-bipyridine. They are also effective for the storage of H₂ gas, both at 77 K and at room temperature.

Original language	English
Pages (from-to)	6305-6308
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	33
DOIs	https://doi.org/10.1002/anie.200701252
State	Published - 2007
Externally published	Yes

Keywords

Copper
Fullerenes
Host-guest systems
Hydrogen storage
Supramolecular chemistry

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10.1002/anie.200701252

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title = "Copper β-diketonate molecular squares and their host-guest reactions",

abstract = "(Figure Presented) All square: Treatment of m-phenylene-bis(β- diketones) with [Cu(NH3)4]2+ yields molecular squares rather than the expected hexagons. The squares react readily with guests such as C60 (see structure) and 4,4′-bipyridine. They are also effective for the storage of H2 gas, both at 77 K and at room temperature.",

keywords = "Copper, Fullerenes, Host-guest systems, Hydrogen storage, Supramolecular chemistry",

author = "Chandi Pariya and Sparrow, \{Christopher R.\} and Back, \{Chang Keun\} and Giselle Sand{\'i} and Fronczek, \{Frank R.\} and Maverick, \{Andrew W.\}",

year = "2007",

doi = "10.1002/anie.200701252",

language = "English",

volume = "46",

pages = "6305--6308",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Copper β-diketonate molecular squares and their host-guest reactions

AU - Pariya, Chandi

AU - Sparrow, Christopher R.

AU - Back, Chang Keun

AU - Sandí, Giselle

AU - Fronczek, Frank R.

AU - Maverick, Andrew W.

PY - 2007

Y1 - 2007

N2 - (Figure Presented) All square: Treatment of m-phenylene-bis(β- diketones) with [Cu(NH3)4]2+ yields molecular squares rather than the expected hexagons. The squares react readily with guests such as C60 (see structure) and 4,4′-bipyridine. They are also effective for the storage of H2 gas, both at 77 K and at room temperature.

AB - (Figure Presented) All square: Treatment of m-phenylene-bis(β- diketones) with [Cu(NH3)4]2+ yields molecular squares rather than the expected hexagons. The squares react readily with guests such as C60 (see structure) and 4,4′-bipyridine. They are also effective for the storage of H2 gas, both at 77 K and at room temperature.

KW - Copper

KW - Fullerenes

KW - Host-guest systems

KW - Hydrogen storage

KW - Supramolecular chemistry

UR - https://www.scopus.com/pages/publications/34548215552

U2 - 10.1002/anie.200701252

DO - 10.1002/anie.200701252

M3 - Article

AN - SCOPUS:34548215552

SN - 1433-7851

VL - 46

SP - 6305

EP - 6308

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 33

ER -

Copper β-diketonate molecular squares and their host-guest reactions

Abstract

Keywords

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