Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle

Daniel M. Ginosar; Lucia M. Petkovic; Kyle C. Burch

doi:10.1016/j.ijhydene.2011.04.164

Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle

Daniel M. Ginosar
, Lucia M. Petkovic
, Kyle C. Burch

Materials, Manufacturing, & Bioenergy S&T

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Eight commercial activated carbon catalysts were examined for their catalytic activity to decompose hydroiodic acid (HI) to produce hydrogen; a key reaction in the sulfur-iodine (S-I) thermochemical water splitting cycle. Activity was examined under a temperature ramp from 473 to 773 K. No statistically significant correlation was found between the measured catalyst sample properties and catalytic activity. Four of the eight samples were examined for one week of continuous operation at 723 K. All samples appeared to be stable over the period of examination.

Original language	English
Pages (from-to)	8908-8914
Number of pages	7
Journal	International Journal of Hydrogen Energy
Volume	36
Issue number	15
DOIs	https://doi.org/10.1016/j.ijhydene.2011.04.164
State	Published - Jul 2011

Keywords

Activated carbon catalyst
Hydrogen production
Hydroiodic acid decomposition
Sulfur-iodine cycle
Thermochemical water splitting

Access to Document

10.1016/j.ijhydene.2011.04.164

Cite this

@article{10284cc9225642a38f5087b7deb7e9b9,

title = "Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle",

abstract = "Eight commercial activated carbon catalysts were examined for their catalytic activity to decompose hydroiodic acid (HI) to produce hydrogen; a key reaction in the sulfur-iodine (S-I) thermochemical water splitting cycle. Activity was examined under a temperature ramp from 473 to 773 K. No statistically significant correlation was found between the measured catalyst sample properties and catalytic activity. Four of the eight samples were examined for one week of continuous operation at 723 K. All samples appeared to be stable over the period of examination.",

keywords = "Activated carbon catalyst, Hydrogen production, Hydroiodic acid decomposition, Sulfur-iodine cycle, Thermochemical water splitting",

author = "Ginosar, \{Daniel M.\} and Petkovic, \{Lucia M.\} and Burch, \{Kyle C.\}",

note = "Funding Information: This work was supported by the U.S. Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office Contract DE-AC07-05ID14517.This manuscript has been authored by Battelle Energy Alliance, LLC under Contract No. DE-AC07-05ID14517 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes.",

year = "2011",

month = jul,

doi = "10.1016/j.ijhydene.2011.04.164",

language = "English",

volume = "36",

pages = "8908--8914",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "15",

}

TY - JOUR

T1 - Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle

AU - Ginosar, Daniel M.

AU - Petkovic, Lucia M.

AU - Burch, Kyle C.

N1 - Funding Information: This work was supported by the U.S. Department of Energy, Office of Nuclear Energy under DOE Idaho Operations Office Contract DE-AC07-05ID14517.This manuscript has been authored by Battelle Energy Alliance, LLC under Contract No. DE-AC07-05ID14517 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a nonexclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes.

PY - 2011/7

Y1 - 2011/7

N2 - Eight commercial activated carbon catalysts were examined for their catalytic activity to decompose hydroiodic acid (HI) to produce hydrogen; a key reaction in the sulfur-iodine (S-I) thermochemical water splitting cycle. Activity was examined under a temperature ramp from 473 to 773 K. No statistically significant correlation was found between the measured catalyst sample properties and catalytic activity. Four of the eight samples were examined for one week of continuous operation at 723 K. All samples appeared to be stable over the period of examination.

AB - Eight commercial activated carbon catalysts were examined for their catalytic activity to decompose hydroiodic acid (HI) to produce hydrogen; a key reaction in the sulfur-iodine (S-I) thermochemical water splitting cycle. Activity was examined under a temperature ramp from 473 to 773 K. No statistically significant correlation was found between the measured catalyst sample properties and catalytic activity. Four of the eight samples were examined for one week of continuous operation at 723 K. All samples appeared to be stable over the period of examination.

KW - Activated carbon catalyst

KW - Hydrogen production

KW - Hydroiodic acid decomposition

KW - Sulfur-iodine cycle

KW - Thermochemical water splitting

UR - https://www.scopus.com/pages/publications/79958778332

U2 - 10.1016/j.ijhydene.2011.04.164

DO - 10.1016/j.ijhydene.2011.04.164

M3 - Article

AN - SCOPUS:79958778332

SN - 0360-3199

VL - 36

SP - 8908

EP - 8914

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 15

ER -

Commercial activated carbon for the catalytic production of hydrogen via the sulfur-Iodine thermochemical water splitting cycle

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this