BaZr0.1Ce0.7Y0.1Yb0.1O3-δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells

Meng Li; Bin Hua; San Ping Jiang; Jian Pu; Bo Chi; Li Jian

doi:10.1016/j.ijhydene.2014.01.132

BaZr_0.1Ce_0.7Y_0.1Yb_0.1O_3-δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells

Meng Li, Bin Hua, San Ping Jiang, Jian Pu, Bo Chi, Li Jian

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

BaZr_0.1Ce_0.7Y_0.1Yb_0.1O_3-δ (BZCYYb) perovskite is synthesized and examined as an alternative anode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) based on direct hydrocarbon fuels, using polarization and electrochemical impedance spectroscopy techniques. Single-phased BZCYYb anode shows an excellent activity for both hydrogen and methane oxidation reactions, achieving a polarization resistance of 0.25 and 0.93 Ω cm², and overpotential of 20 and 202 mV at 100 mA cm^-2 and 750 °C in wet H₂ (3% H₂O/97% H₂) and wet CH₄ (3% H₂O/97% CH₄), respectively. The electrocatalytic activity of BZCYYb anodes is significantly higher than that of the (La,Sr)(Cr,Mn)O₃ anodes as reported in the literature. Furthermore, BZCYYb exhibits excellent resistance to carbon deposition. The present study demonstrates that BZCYYb perovskite is a promising alternative anode material for direct hydrocarbon fuels based SOFCs.

Original language	English
Pages (from-to)	15975-15981
Number of pages	7
Journal	International Journal of Hydrogen Energy
Volume	39
Issue number	28
DOIs	https://doi.org/10.1016/j.ijhydene.2014.01.132
State	Published - Sep 23 2014
Externally published	Yes

Keywords

Alternative anode
BZCYYb
Carbon tolerance
Electrochemical performance
Methane
Solid oxide fuel cells

Access to Document

10.1016/j.ijhydene.2014.01.132

Cite this

@article{cf1fde6de7da4dbd926de8ae47ee1ef1,

title = "BaZr0.1Ce0.7Y0.1Yb0.1O3-δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells",

abstract = "BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb) perovskite is synthesized and examined as an alternative anode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) based on direct hydrocarbon fuels, using polarization and electrochemical impedance spectroscopy techniques. Single-phased BZCYYb anode shows an excellent activity for both hydrogen and methane oxidation reactions, achieving a polarization resistance of 0.25 and 0.93 Ω cm2, and overpotential of 20 and 202 mV at 100 mA cm-2 and 750 °C in wet H2 (3% H2O/97% H2) and wet CH4 (3% H2O/97% CH4), respectively. The electrocatalytic activity of BZCYYb anodes is significantly higher than that of the (La,Sr)(Cr,Mn)O3 anodes as reported in the literature. Furthermore, BZCYYb exhibits excellent resistance to carbon deposition. The present study demonstrates that BZCYYb perovskite is a promising alternative anode material for direct hydrocarbon fuels based SOFCs.",

keywords = "Alternative anode, BZCYYb, Carbon tolerance, Electrochemical performance, Methane, Solid oxide fuel cells",

author = "Meng Li and Bin Hua and Jiang, {San Ping} and Jian Pu and Bo Chi and Li Jian",

year = "2014",

month = sep,

day = "23",

doi = "10.1016/j.ijhydene.2014.01.132",

language = "English",

volume = "39",

pages = "15975--15981",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "28",

}

TY - JOUR

T1 - BaZr0.1Ce0.7Y0.1Yb0.1O3-δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells

AU - Li, Meng

AU - Hua, Bin

AU - Jiang, San Ping

AU - Pu, Jian

AU - Chi, Bo

AU - Jian, Li

PY - 2014/9/23

Y1 - 2014/9/23

N2 - BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb) perovskite is synthesized and examined as an alternative anode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) based on direct hydrocarbon fuels, using polarization and electrochemical impedance spectroscopy techniques. Single-phased BZCYYb anode shows an excellent activity for both hydrogen and methane oxidation reactions, achieving a polarization resistance of 0.25 and 0.93 Ω cm2, and overpotential of 20 and 202 mV at 100 mA cm-2 and 750 °C in wet H2 (3% H2O/97% H2) and wet CH4 (3% H2O/97% CH4), respectively. The electrocatalytic activity of BZCYYb anodes is significantly higher than that of the (La,Sr)(Cr,Mn)O3 anodes as reported in the literature. Furthermore, BZCYYb exhibits excellent resistance to carbon deposition. The present study demonstrates that BZCYYb perovskite is a promising alternative anode material for direct hydrocarbon fuels based SOFCs.

AB - BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (BZCYYb) perovskite is synthesized and examined as an alternative anode material for intermediate temperature solid oxide fuel cells (IT-SOFCs) based on direct hydrocarbon fuels, using polarization and electrochemical impedance spectroscopy techniques. Single-phased BZCYYb anode shows an excellent activity for both hydrogen and methane oxidation reactions, achieving a polarization resistance of 0.25 and 0.93 Ω cm2, and overpotential of 20 and 202 mV at 100 mA cm-2 and 750 °C in wet H2 (3% H2O/97% H2) and wet CH4 (3% H2O/97% CH4), respectively. The electrocatalytic activity of BZCYYb anodes is significantly higher than that of the (La,Sr)(Cr,Mn)O3 anodes as reported in the literature. Furthermore, BZCYYb exhibits excellent resistance to carbon deposition. The present study demonstrates that BZCYYb perovskite is a promising alternative anode material for direct hydrocarbon fuels based SOFCs.

KW - Alternative anode

KW - BZCYYb

KW - Carbon tolerance

KW - Electrochemical performance

KW - Methane

KW - Solid oxide fuel cells

UR - http://www.scopus.com/inward/record.url?scp=84908245173&partnerID=8YFLogxK

U2 - 10.1016/j.ijhydene.2014.01.132

DO - 10.1016/j.ijhydene.2014.01.132

M3 - Article

AN - SCOPUS:84908245173

SN - 0360-3199

VL - 39

SP - 15975

EP - 15981

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 28

ER -

BaZr_0.1Ce_0.7Y_0.1Yb_0.1O_3-δ as highly active and carbon tolerant anode for direct hydrocarbon solid oxide fuel cells

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this