An electrochemical STM study of coarsening and corrosion of platinum films

Q. Xu, E. Kreidler, D. O. Wipf, T. He

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

In-situ electrochemical scanning tunneling microscopy is used to study the coarsening of platinum crystals under potentiostating and the dissolution and coarsening of platinum crystals through potential cycling. A rapid coarsening of platinum crystals was observed for potentiostating in the double-layer region. It is suggested that the coarsening is a variant of Ostwald ripening dominated by surface-diffusion transport. In addition, potential cycling not only causes surface platinum dissolution as a result of the platinum redox reaction but also platinum crystal ripening. Details of the platinum surface restructuring are described and the possible influences of these phenomena on fuel cell operation are discussed.

Original languageEnglish
Title of host publicationECS Transactions - 7th Symposium Devoted to Proton Exchange Membrane Fuel Cells
Pages1279-1287
Number of pages9
Edition1 PART 2
DOIs
StatePublished - 2007
Event7th Symposium Devoted to Proton Exchange Membrane Fuel Cells - 212th ECS Meeting - Washington, DC, United States
Duration: Oct 7 2007Oct 12 2007

Publication series

NameECS Transactions
Number1 PART 2
Volume11
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

Conference

Conference7th Symposium Devoted to Proton Exchange Membrane Fuel Cells - 212th ECS Meeting
Country/TerritoryUnited States
CityWashington, DC
Period10/7/0710/12/07

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